Bis[2,6-bis­(1H-benzimidazol-2-yl)pyridine]­nickel(II) dipicrate dimethyl­formamide disolvate

نویسندگان

  • Xingcai Huang
  • Fan Kou
  • Baoliang Qi
  • Xuan Meng
  • Huilu Wu
چکیده

In the title compound, [Ni(C(19)H(13)N(5))(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Ni(II) ion is coordinated by two tridentate 2,6-bis-(1H-benzimidazol-2-yl)pyridine ligands in a distorted octa-hedral geometry. In the crystal structure, the picrate anions and solvent dimethyl-formamide (DMF) mol-ecules are connected to the cation via inter-molecular N-H⋯O hydrogen bonds. Further stabilization is provided by weak inter-molecular C-H⋯O hydrogen bonds. One of the DMF moleclues is disordered over two sites with refined occupancies of 0.737 (3) and 0.263 (3).

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010